Infrared measurements help HVO scientists unravel Kilauea’s gas chemistry

Most people in Hawaii know about sulfur dioxide (SO2) gas, the major component of vog. But, have you ever found yourself wanting to know the SO2/HCl (sulfur dioxide/hydrogen chloride) ratio in volcanic gas? Or the amount of CO2 (carbon dioxide) dissolved in volcanic glass?

If you’re not a volcanologist or geologist, probably not. But at the USGS Hawaiian Volcano Observatory (HVO), we do need to know those things. Magma contains dissolved gases, or volatiles, which drive eruptions. And while gases in the air and dissolved volatiles in molten magma (preserved as glass and glass inclusions in minerals) may not seem like they’d be measured the same way, we can use the same principles and techniques to measure both and help us understand eruptive activity.

To make each of those types of volatile measurements, we use an instrument called a Fourier Transform Infrared spectrometer, or FTIR. FTIR instruments detect incoming infrared (IR) radiation — the type of radiation associated with hot/warm objects, having wavelengths slightly longer than the visible light we can see with our eyes.

But how can we tell which gases are there?

It turns out that gases absorb radiation, and each gas — like CO2, HCl, SO2, H2O (water vapor), and others — has its own unique signature of how much it absorbs at different wavelengths.

One slightly different, but common, example of an absorbing gas that many people know about is ozone (O3). Ozone in the atmosphere protects us from some of the sun’s harmful ultraviolet (UV) radiation (shorter wavelengths than visible light) by absorbing UV wavelengths very strongly. SO2 also absorbs strongly in the UV range; HVO uses UV to measure SO2 emission rates.

However, many important volcanic volatiles don’t absorb UV very well, but they do absorb strongly in the IR range. So, we turn to FTIR to measure them. Or, more precisely, one of our two FTIRs! Yes, HVO has two different types of FTIR, which we use for different applications.

For measuring gases in air, we take our “field FTIR” and head out to where the volcanic plume is. We need a source of IR energy and, luckily, lava is a great source of IR because it’s so hot. So, when we have an eruption, we can aim the FTIR at hot, glowing lava. If there’s no lava around, we can still measure the gas by aiming the FTIR at a special lamp that generates IR.

Once we have the IR source, we need to position the FTIR so the volcanic gas is between the IR source and the FTIR. The FTIR measures relative amounts of IR radiation at different wavelengths, some of which is absorbed by the volcanic gases. We then process the data and calculate important gas ratios, like CO2/SO2 and SO2/HCl, which can give us information about how magma and volatiles are transported in the volcanic plumbing system.

But what about the other FTIR?

That would be our “lab FTIR,” which doesn’t venture out near the volcanic plume like the ‘field FTIR’ does. Instead, the ‘lab FTIR’ is used for measuring small amounts of H2O and CO2 dissolved in minerals and volcanic glass.

The principles are the same — the lab FTIR has an IR source and a radiation detector that measures IR intensity at many different wavelengths. But instead of a volcanic plume passing between them, we insert a tiny, carefully polished chip of mineral or glass into the path between the IR source and the detector.

Minerals and glasses — especially those that erupt out of gas-rich volcanoes — often have CO2 and H2O still dissolved in them, which will absorb IR at those characteristic wavelengths just like volcanic gases in the air. As long as we know how thick the tiny chip of glass or mineral is, the FTIR can then tell us how much of those gases are dissolved in those little solid pieces. Once we know that, we can determine things like how deep that erupted material came from and how quickly it erupted.

The “lab FTIR” purchase was made possible by funding from the Additional Supplemental Appropriations for Disaster Relief Act of 2019 (H.R. 2157) in the wake of the 2018 Kilauea eruption.

Even if Santa doesn’t bring you an FTIR this year, don’t worry — HVO has two, and we will keep using them to learn more about the volcanoes here in Hawaii, their eruptions, and the gases that drive them.

Volcano Activity Updates

Kilauea volcano is erupting. Its USGS Volcano Alert level is at WATCH. Kilauea updates are issued daily.

Lava continues to erupt from a single vent in the western wall of Halema‘uma‘u crater after a two-day pause in activity. All lava activity is confined within Halema‘uma‘u crater in Hawaii Volcanoes National Park. Sulfur dioxide emission rates remain elevated and were measured at approximately 130 tons per day on Dec. 21. Seismicity is elevated but stable, with few earthquakes and ongoing volcanic tremor. Summit tiltmeter data has remained relatively flat over the past week, with brief inflationary and deflationary signals early this week.

Mauna Loa is not erupting and remains at Volcano Alert Level ADVISORY. This alert level does not mean that an eruption is imminent or that progression to an eruption from the current level of unrest is certain. Mauna Loa updates are issued weekly.

This past week, about 113 small-magnitude earthquakes were recorded below the summit and upper elevation flanks of Mauna Loa — the majority of these occurred at shallow depths less than 6 miles. GPS measurements show no major deformation over the past week. Gas concentrations and fumarole temperatures at both the summit and at Sulphur Cone on the Southwest Rift Zone remain stable. Webcams show no changes to the landscape.

There were four events with three or more felt reports in the Hawaiian Islands during the past week: a magnitude-3.3 earthquake 4 miles E of Pahala on Dec. 17 at 2:25 p.m., a magnitude-3.1 earthquake 1 mile SSE of Pahala on Dec. 17 at 8:49 a.m., a magnitude-3.5 earthquake 4 miles ENE of Pahala on Dec. 17 at 8:27 a.m., and a magnitude-3.5 earthquake 4 miles E of Pahala on Dec. 17 at 4:17 a.m.

Visit https://www.usgs.gov/observatories/hawaiian-volcano-observatory for past Volcano Watch articles, updates, photos, maps, recent earthquake info, and more. Email questions to askHVO@usgs.gov. Volcano Watch is a weekly article and activity update written by USGS Hawaiian Volcano Observatory scientists and affiliates.